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Calculate the pH when 200.0 mL of a 1.00 M solution of H2A (Ka1 = 1.0 × 10-6, Ka2 = 1.0 × 10-10) is titrated with the following volumes of 1.00 M NaOH. -200.0 mL of 1.00 M NaOH


A) 9.50
B) 6.48
C) 6.00
D) 8.00
E) none of these

F) A) and B)
G) A) and C)

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What is the molarity of a sodium hydroxide solution if 25.0 mL of this solution reacts exactly with 22.30 mL of 0.253 M sulfuric acid?


A) 0.284 M
B) 0.451 M
C) 0.567 M
D) 0.226 M
E) 0.113 M

F) A) and D)
G) A) and C)

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One milliliter (1.00 mL) of acid taken from a lead storage battery is pipetted into a flask. Water and phenolphthalein indicator are added, and the solution is titrated with 0.38 M NaOH until a pink color appears; 15.8 mL is required. Find, to within 5%, the number of grams of H2SO4 (formula weight = 98) present in 1 L of the battery acid.


A) 480 g
B) 240 g
C) 580 g
D) 290 g
E) 750 g

F) C) and E)
G) B) and C)

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Which of the following salts shows the lowest solubility in water? Ksp values are as follows: Ag2S = 1.6 × 10-49; Bi2S3 = 1.0 × 10-72; HgS = 1.6 × 10-54; Mg(OH) 2 = 8.9 × 10-12; MnS = 2.3 × 10-13)


A) HgS
B) MnS
C) Bi2S3
D) Ag2S
E) Mg(OH) 2

F) B) and E)
G) None of the above

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A 0.012-mol sample of Na2SO4 is added to 400 mL of each of two solutions. One solution contains 1.5 × 10-3 M BaCl2; the other contains 1.5 × 10-3 M CaCl2. Ksp for BaSO4 = 1.5 × 10-9 and Ksp for CaSO4 = 6.1 × 10-5. Which of the following statements is true?


A) Both BaSO4 and CaSO4 would precipitate.
B) Not enough information is given to determine whether precipitation would occur.
C) CaSO4 would precipitate but BaSO4 would not.
D) BaSO4 would precipitate but CaSO4 would not.
E) Neither BaSO4 nor CaSO4 would precipitate.

F) A) and B)
G) B) and D)

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Consider the titration of 100.0 mL of 0.250 M aniline (Kb = 3.8 × 10-10) with 0.500 M HCl. Calculate the pH of the solution at the stoichiometric point.


A) 8.70
B) 2.68
C) 11.62
D) -0.85
E) none of these

F) A) and D)
G) B) and C)

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You are given a solution of the weak base Novocain, Nvc. Its pH is 11.00. You add to the solution a small amount of a salt containing the conjugate acid of Novocain, NvcH+. Which statement is true?


A) The pH and the pOH remain unchanged.
B) The pH and the pOH both decrease.
C) The pH and the pOH both increase.
D) The pH increases and pOH decreases.
E) The pH decreases and the pOH increases.

F) A) and E)
G) B) and E)

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A 200.0-mL sample of the weak acid H3A (0.100 M) is titrated with 0.200 M NaOH. What are the major species at each of the following points in the titration? (Water is always assumed to be a major species.) -After 300.0 mL of 0.200 M NaOH is added


A) A3-
B) OH-, A3-
C) H3A, H2A-, HA2-, A3-
D) H2A-, OH-
E) OH-, HA2-, A3-

F) A) and C)
G) A) and B)

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You have solutions of 0.200 M HNO2 and 0.200 M KNO2 (Ka for HNO2 = 4.00 × 10-4) . A buffer of pH 3.000 is needed. What volumes of HNO2 and KNO2 are required to make 1 L of buffered solution?


A) 286 mL HNO2; 714 mL KNO2
B) 714 mL HNO2; 286 mL KNO2
C) 413 mL HNO2; 587 mL KNO2
D) 500 mL of each
E) 587 mL HNO2; 413 mL KNO2

F) A) and C)
G) B) and E)

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Consider the following information about the diprotic acid ascorbic acid (H2As for short, molar mass = 176.1) . Consider the following information about the diprotic acid ascorbic acid (H<sub>2</sub>As for short, molar mass = 176.1) .   The titration curve for disodium ascorbate, Na<sub>2</sub>As, with standard HCl is shown below:   -What is the pH at point I (V<sub>1</sub>/2 HCl added) ? A)  7.95 B)  12.39 C)  10 D)  11.79 E)  none of these The titration curve for disodium ascorbate, Na2As, with standard HCl is shown below: Consider the following information about the diprotic acid ascorbic acid (H<sub>2</sub>As for short, molar mass = 176.1) .   The titration curve for disodium ascorbate, Na<sub>2</sub>As, with standard HCl is shown below:   -What is the pH at point I (V<sub>1</sub>/2 HCl added) ? A)  7.95 B)  12.39 C)  10 D)  11.79 E)  none of these -What is the pH at point I (V1/2 HCl added) ?


A) 7.95
B) 12.39
C) 10
D) 11.79
E) none of these

F) A) and D)
G) A) and B)

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The contents of the flask are transferred quantitatively to a 2L volumetric. 100ml of 1 M HCL is added and the flask filled to the mark with water. There is still observable solid calcium hydroxide in the bottom of the new flask. What is the pH of this solution?


A) 2.94
B) 12.14
C) 2.16
D) 7.00
E) 11.83

F) A) and E)
G) A) and D)

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A 50.00-mL sample of 0.100 M Ca(NO3) 2 is mixed with 50.00 mL of 0.200 M NaF. When the system has come to equilibrium, which of the following sets of conditions will hold? The Ksp for CaF2 is 4.0 × 10-11. A 50.00-mL sample of 0.100 M Ca(NO<sub>3</sub>) <sub>2</sub> is mixed with 50.00 mL of 0.200 M NaF. When the system has come to equilibrium, which of the following sets of conditions will hold? The K<sub>sp</sub> for CaF<sub>2</sub> is 4.0 × 10<sup>-11</sup>.   A)  10.0 × 10<sup>-3</sup> 1.3 × 10<sup>-5</sup> M 1.3 × 10<sup>-5</sup> M B)  5.0 × 10<sup>-3</sup> 3.5 × 10<sup>-4</sup> M 7.0 × 10<sup>-4</sup> M C)  5.0 × 10<sup>-3</sup> 2.2 × 10<sup>-4</sup> M 4.3 × 10<sup>-4</sup> M D)  5.0 × 10<sup>-3</sup> 3.5 × 10<sup>-4</sup> M 4.3 × 10<sup>-4</sup> M E)  5.0 × 10<sup>-3</sup> 3.4 × 10<sup>-9</sup> M 5.0 × 10<sup>-2</sup> M


A) 10.0 × 10-3 1.3 × 10-5 M 1.3 × 10-5 M
B) 5.0 × 10-3 3.5 × 10-4 M 7.0 × 10-4 M
C) 5.0 × 10-3 2.2 × 10-4 M 4.3 × 10-4 M
D) 5.0 × 10-3 3.5 × 10-4 M 4.3 × 10-4 M
E) 5.0 × 10-3 3.4 × 10-9 M 5.0 × 10-2 M

F) A) and B)
G) B) and D)

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Calculate the pH when 200.0 mL of a 1.00 M solution of H2A (Ka1 = 1.0 × 10-6, Ka2 = 1.0 × 10-10) is titrated with the following volumes of 1.00 M NaOH. -300.0 mL of 1.00 M NaOH


A) 10.00
B) 11.21
C) 9.50
D) 9.30
E) none of these

F) B) and E)
G) B) and D)

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Differentiate between the equivalence point and the endpoint in an acid-base titration.

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See Sectio...

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Calculate the pH when 200.0 mL of a 1.00 M solution of H2A (Ka1 = 1.0 × 10-6, Ka2 = 1.0 × 10-10) is titrated with the following volumes of 1.00 M NaOH. -0 mL of 1.00 M NaOH


A) 3.00
B) 6.00
C) 0
D) 3.35
E) none of these

F) All of the above
G) None of the above

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A titration of 100.0 mL of 1.00 M malonic acid (H2A) was done with 1.00 M NaOH. For malonic acid, Ka1 = 1.49 × 10-2, Ka2 = 2.03 × 10-6. -Calculate [H+] after 300.0 mL of 1.00 M NaOH has been added.


A) 1.00 × 10-7 M
B) 4.00 × 10-14 M
C) 1.41 × 10-10 M
D) 1.00 M
E) none of these

F) C) and D)
G) A) and E)

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A 50.0-mL sample of 2.0 × 10-4 M CuNO3 is added to 50.0 mL of 4.0 M NaCN. Cu+ reacts with CN- to form the complex ion Cu(CN) 32-: A 50.0-mL sample of 2.0 × 10<sup>-4</sup> M CuNO<sub>3</sub> is added to 50.0 mL of 4.0 M NaCN. Cu<sup>+</sup> reacts with CN<sup>-</sup> to form the complex ion Cu(CN) <sub>3</sub><sup>2-</sup>:   Calculate the solubility of CuBr(s)  (K<sub>sp</sub> = 1.0 × 10<sup>-5</sup>)  in 1.0 L of 1.0 M NaCN. A)  0.33 mol/L B)  1.0 × 10<sup>-6</sup> mol/L C)  1.0 × 10<sup>3</sup> mol/L D)  1.0 mol/L E)  none of these Calculate the solubility of CuBr(s) (Ksp = 1.0 × 10-5) in 1.0 L of 1.0 M NaCN.


A) 0.33 mol/L
B) 1.0 × 10-6 mol/L
C) 1.0 × 103 mol/L
D) 1.0 mol/L
E) none of these

F) B) and E)
G) None of the above

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Calculate the concentration of [H+] of a buffered solution containing 5.0 × 10−4 M HCN (Ka = 6.2 × 10−10) and 1.5 × 10−4 M NaCN.


A) 3.06 × 10−9 M​
B) ​0.22 × 10−9 M
C) 2.07 × 10−9 M
D) 4.12 × 10−9 M
E) 4.58 × 10−9 M

F) A) and E)
G) A) and B)

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A 200-mL solution contains 0.018 mol each of I-, Br-, and Cl-. When the solution is mixed with 200 mL of 0.24 M AgNO3, how much AgCl(s) precipitates out? A 200-mL solution contains 0.018 mol each of I<sup>-</sup>, Br<sup>-</sup>, and Cl<sup>-</sup>. When the solution is mixed with 200 mL of 0.24 M AgNO<sub>3</sub>, how much AgCl(s)  precipitates out?   A)  2.6 g B)  0.0 g C)  3.3 g D)  5.0 g E)  1.7 g


A) 2.6 g
B) 0.0 g
C) 3.3 g
D) 5.0 g
E) 1.7 g

F) B) and D)
G) A) and E)

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In the titration of 100.0 mL of a 0.200 M solution of H2A (Ka1 = 1.0 × 10-5, Ka2 = 1.0 × 10-8) , what volume of 0.400 M NaOH must be added to reach a pH of 5.00?


A) 25.0 mL
B) 100.0 mL
C) 0 mL
D) 150.0 mL
E) 50.0 mL

F) C) and D)
G) All of the above

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